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Arsine (AsH3)

This page presents information about arsine – or arsenic trihydride – (AsH3), appropriate detection tools – Arsine gas detector -and respiratory protective equipment (gas mask or powered air respirator with B gas filter).

Arsine gas detector ans AsH3 respiratory protection, PAPR and gas mask

Principales caractéristiques de l’arsine

Historically known for being used during the First World War as a chemical weapon, arsine (AsH3) – also known as arsenic trihydride – is present in many industrial processes. It is notably used in the steel industry in ferrous metal foundries (desulfurization systems cleaning), tin foundries, metal treatment, electronics sector and boiler descaling).

CAS TWA (8 hours) STEL (15 minutes) LEL IP Density / Air Filter / SCBA
7784-42-1 0.05 ppm 0.2 ppm 5.1 % 9.89 eV 2.7 B

Arsine effects on health

Colorless at ambient temperature, arsine (AsH3) is odorless at nascent state. Once in contact with air, it oxidizes and gets a pronounced garlic smell. As it is heavier than air, it penetrates organisms through the breathing tracts. Arsine is highly toxic when inhaled (R26) and harmful for the aquatic environment as it easily dissolves into water. Extremely flammable (R12), it can compose explosive mixtures between 5.1 and 78% volume..

Arsine effects on health, why use an  arsine gas detector and AsH3 respirator

Arsine effects on health (AsH3)

Arsine gas detector (AsH3)

Despite its garlic fragrance, only an arsine gas detector can accurately measure concentrations of this gas. Even if it is explosive at 5.1% volume, an LEL measurement would be useless as this gas is highly toxic. Thus an arsine detection system in ppm or ppb should be selected.

The BM25 area gas monitor can detect from 1 up to 5 gases. This powerful gas detector is not a personal protective equipment but a collective area protective equipment.

  • Portable gas detector BM25
  • Weekly or monthly rental
  • ATEX multigas area monitor
  • Detection of AsH3, CO2, COCl2, combustible gases, H2, HCN, HCl, HF, H2S, NO, NO2, O2, PH3, SO2, VOC
  • Configurable according to your needs
  • Provided with every accessory
  • Additional information
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Area gas monitor – BM25

The BM25 area gas monitor can detect from 1 up to 5 gases. This powerful gas detector is not a personal protective equipment but a collective area protective equipment.

Portable gas detector BM25
  • Weekly or monthly rental
  • ATEX multigas area monitor
  • Detection of AsH3, CO2, COCl2, combustible gases, H2, HCN, HCl, HF, H2S, NO, NO2, O2, PH3, SO2, VOC
  • Configurable according to your needs
  • Provided with every accessory
Additional information

As its name implies, the BM25 area gas monitor is designed to monitor a specific zone were people are working. In its 4 gas version, the BM25 features an autonomy of around 100 hours and is fully charged within 4 hours.

According to the most specific needs, many configurations are available. The BM25 area gas monitor indeed features a large range of sensors to detect up to 5 gases like arsine (AsH3), carbon dioxide (CO2), phosgene (COCl2), the combustible gases, hydrogene (H2), hydrogene cyanide (HCN), hydrogene chloride (HCl), hydrogene fluoride (HF), hydrogen sulfide (H2S), nitric oxide (NO), nitrogen dioxide (NO2), oxygene (O2), phosphine (PH3), sulfur dioxide (SO2) and the volatile organic compounds (VOC).

In order to alert every worker evolving in the monitored area of any gas hazard, the BM25 area gas monitor features a two-way 103 dB audible alarm at one meter. A high visibility red light is added to the safety unit to evolve safely in noisy and/or dark areas.

The BM25 is equipped with a backlit graphic LCD display for better reading of values. The "FLIP-FLAP" function (display reversal depending on the area monitor position) is also integrated. As it is made with robust material, the BM25 suits in the harshest environments and is compiant with the IP66 ingress protection level. Is also meets major current EU ATEX standards.

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Portasens II is a rare gases leak detector with interchangeable sensors. This calibration-free detector is equipped with an internal sampling pump to accurately monitor around thirty gases.

  • Portable gas detector PortasenseII
  • Gas leak detection of alcohol, B2H6, Br2, C2H2, CH2O, Cl2, ClO2, CO, COCl2, F2, acid gas, GeH4, H2, H2O2, H2S, HCl, HF, NH3, NO, NO2, O2, O3, PH3, SiH4
  • Power supply: D alkaline battery (75 hours runtime) and rechargeable battery
  • 3 visual and audible alarms (alarm 1, alarm 2 and adjustable alarm)
  • Outputs: RS232 for data downloading on a PC
  • Additional information
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Rare gases leak detector – PORTASENS II

Portasens II is a rare gases leak detector with interchangeable sensors. This calibration-free detector is equipped with an internal sampling pump to accurately monitor around thirty gases.

Portable gas detector PortasenseII
  • Gas leak detection of alcohol, B2H6, Br2, C2H2, CH2O, Cl2, ClO2, CO, COCl2, F2, acid gas, GeH4, H2, H2O2, H2S, HCl, HF, NH3, NO, NO2, O2, O3, PH3, SiH4
  • Power supply: D alkaline battery (75 hours runtime) and rechargeable battery
  • 3 visual and audible alarms (alarm 1, alarm 2 and adjustable alarm)
  • Outputs: RS232 for data downloading on a PC
Additional information

PortaSense II gas leak detector is a single-gas detector to monitor rare gases. This device is powered with a D alkaline battery for around 75 hours runtime and an internal Nicad battery with an autonomy of around 6 hours.

The PortaSense gas leak detector can detect many gases thanks to its large range of interchangeable sensors. Majors detected gases are: alcohol, B2H6, Br2, C2H2, CH2O, Cl2, ClO2, CO, COCl2, F2, acid gas, GeH4, H2, H2O2, H2S, HCl, HF, NH3, NO, NO2, O2, O3, PH3, SiH4. In complement to this detected gases, this monitor features different measuring ranges for every gas.

The PortaSense II primarily detect gas leaks with its integrated sampling pump. This enables accurate measurements of hazardous gas concentrations. This gas leak detector with interchangeable sensors is moreover calibration-free, which makes it very versatile.

This single-gas detector features audible and audible alarms with 3 levels: caution, warning, and alarm with adjustable setpoints. A fourth alarm will indicate a low flow or low battery.

Thanks to its internal memory, the detector can record event data during 8 days with 1 minute interval. Furthermore, Portasense II features an RS32 output to connect a PC for data downloading.

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4-20 mA gas detector / transmitter with integrated sampling pump, pre-calibrated cartridge, alarm relays and TCP/IP communication.

Detection of AsH3, B2H6, BCl3, BF3, Br2, C2H4O, Cl2, ClF3, ClO2, CO, COCl2, F2, GeH4, H2, H2S, H2Se, HBr, HCl, HCN, HF, HMDS, N2H4, NH3, NO, NO2, O2, O3, PH3, POCl3, Si2H6, SiCl4, SiHCl3, SO2, TEOS, TMB, TMP, WF6

  • Fixed gas detector Midas
  • Detection with pyrolysis module of C4F6, C5H8, CH3F, DCE 1.2, NF3, SF6
  • Integrated aspirated pump: 500 mL/min flow
  • 3 configurable NO or NF alarm relays
  • High accuracy measurement from ppb to ppm
  • Ethernet (PoE) TCP/IP and Modbus communication
  • Additional information
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Midas gas detector with sampling pump

4-20 mA gas detector / transmitter with integrated sampling pump, pre-calibrated cartridge, alarm relays and TCP/IP communication.

Detection of AsH3, B2H6, BCl3, BF3, Br2, C2H4O, Cl2, ClF3, ClO2, CO, COCl2, F2, GeH4, H2, H2S, H2Se, HBr, HCl, HCN, HF, HMDS, N2H4, NH3, NO, NO2, O2, O3, PH3, POCl3, Si2H6, SiCl4, SiHCl3, SO2, TEOS, TMB, TMP, WF6

Fixed gas detector Midas
  • Detection with pyrolysis module of C4F6, C5H8, CH3F, DCE 1.2, NF3, SF6
  • Integrated aspirated pump: 500 mL/min flow
  • 3 configurable NO or NF alarm relays
  • High accuracy measurement from ppb to ppm
  • Ethernet (PoE) TCP/IP and Modbus communication
Additional information

Operating with a reliable gas detection technology, the Midas fixed gas detector has been especially designed to monitor the presence of flammable and toxic gases in ambient air. This way, this detector can monitor following gases: arsine (AsH3), diborane (B2H6), boron trichloride (BCl3), boron trifluoride (BF3), bromine (Br2), ethylene oxide (C2H4O), chlorine (Cl2), chlorine trifluoride (ClF3), chlorine dioxide (ClO2), carbon monoxide (CO), chlorine dioxide (COCl2), fluorine (F2), germane (GeH4), hydrogen (H2), hydrogen sulfide (H2S), hydrogen selenide (H2Se), hydrogen bromide (HBr), hydrogen chloride (HCl), hydrogen cyanide (HCN), hydrogen fluoride (HF), hexamethyldisilazan (HMDS), hydrazine (N2H4), ammonia (NH3), nitric oxyde (NO), nitrogen dioxide (NO2), oxygen (O2), ozone (O3), phosphine (PH3), phosphoryl chloride (POCl3), disilane (Si2H6), silicon tetrachloride (SiCl4), trichlorosilane (SiHCl3), sulfur dioxide (SO2), tetra ethyl ortho silicate (TEOS), trimethylborane (TMB), TMP, tungsten hexafluoride (WF6).

 

Moreover, with its optional pyrolyzer module, Midas is able to detect following gases: hexafluorobutadiene (C4F6), octofluorocyclopentene (C5H8), methyl fluoride (CH3F), DCE 1.2, nitrogen trifluoride (NF3), sulfur hexafluoride (SF6).

 

Compact and featuring a zinc-plated steel base, the Midas is easy to install. Small, compact and lightweight, this detector suits perfectly in applications like light industries, laboratories, semiconductor transformation or even the wastewater treatment. Its pump system has a 2 year lifetime and can draw samples up to 30 meters.

 

Its alphanumeric backlit LCD with intuitive icon menu can display the concentrations and its datalogger enables operators to download vents and sensor history.

 

Its smart sensor with on board calibration certificate are ready for use and can be easily and quickly replaced.

 

Midas fixed gas detector features several outputs: visual, 3 built in relays for alarm 1, 2 and fault, analog and digital communication and is powered through Ethernet connection (PoE). It can be wired with 4-20 mA 2 to 4 wires or digitally with CAT5 cabling or equivalent with RJ45 connector.

 

Lastly, Midas is CE marked for a total immunity to electromagnetic interferences.

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The Satellite XT is a fixed gas detector with interchangeable sensors. It is especially designed to continuously monitor hazardous concentrations of gases.

Detected gases: AsH3, BBr3, B2H6, BCl3, BF3, Br2, C2H4O, Cl2, ClF3, ClO2, CO, COCl2, F2, GeH4, H2, H2S, H2Se, HBr, HCl, HCN, HF, HMDS, MCF, MMH, N2H4, NH3, NO, NO2, O2, O3, PH3, POCl3, SiCl4, SiHCl3, SO2,TBA, TBP, TDMAT, TEOS, TMB, TMP, UDMH, WF6.

  • Fxed gas detector Satellite XT
  • Pyrolysis module detection: C4F6, C5F8, CH3F, DCE 1.2, NF3, SF6
  • Pre-calibrated interchangeable sensors, easy maintenance
  • 4-20mA linear output
  • 3 optional single-pole relays
  • Optional remote measure (up to 3 meters)
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Toxic corrosive & combustible gas detector – satellite xt

The Satellite XT is a fixed gas detector with interchangeable sensors. It is especially designed to continuously monitor hazardous concentrations of gases.

Detected gases: AsH3, BBr3, B2H6, BCl3, BF3, Br2, C2H4O, Cl2, ClF3, ClO2, CO, COCl2, F2, GeH4, H2, H2S, H2Se, HBr, HCl, HCN, HF, HMDS, MCF, MMH, N2H4, NH3, NO, NO2, O2, O3, PH3, POCl3, SiCl4, SiHCl3, SO2,TBA, TBP, TDMAT, TEOS, TMB, TMP, UDMH, WF6.

Fxed gas detector Satellite XT
  • Pyrolysis module detection: C4F6, C5F8, CH3F, DCE 1.2, NF3, SF6
  • Pre-calibrated interchangeable sensors, easy maintenance
  • 4-20mA linear output
  • 3 optional single-pole relays
  • Optional remote measure (up to 3 meters)
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AsH3 respiratory protection (Arsine)

As arsine is very irritating to the eyes, it is highly recommended to wear a full-face mask for short-term applications or a more comfortable powered air purifying respirator with B gas filter. If concentrations exceed 60 times the OEL, a self-contained breathing apparatus is required.

The Duraflow powered air respirator is a versatile solution for hazardous workspaces. It provides a quality respiratory protection for a fair price.

  • The powered air purifying respirator Duraflow PAPR
  • Compatibility with RD DIN 40 universal filter cartridges
  • Rechargeable battery – 2 available version: 8 or 16 hours runtime
  • Automatic airflow regulation (160l/min)
  • Visual alarms, notifications and display
  • CEN1294 & CE0086 certified, IP55/IP67
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Powered air purifying respirator Duraflow

The Duraflow powered air respirator is a versatile solution for hazardous workspaces. It provides a quality respiratory protection for a fair price.

The powered air purifying respirator Duraflow PAPR
  • Compatibility with RD DIN 40 universal filter cartridges
  • Rechargeable battery – 2 available version: 8 or 16 hours runtime
  • Automatic airflow regulation (160l/min)
  • Visual alarms, notifications and display
  • CEN1294 & CE0086 certified, IP55/IP67
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The SARI gas mask provides operating comfort and efficient protection against toxic gases and particles (solid, radioactive, smokes), bacteria and virus.

  • Compatible with PRO2000 filter range (gas, particle and combined)
  • Central phonic membrane for easy communication
  • Compatible with powered air equipment
  • Internal mask with non-return and anti-fog valves, reduces CO2
  • Fully adjustable 5 points harness for improved operating comfort
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Full face gas mask – SARI

The SARI gas mask provides operating comfort and efficient protection against toxic gases and particles (solid, radioactive, smokes), bacteria and virus.

masque sari contre les gaz toxiques et vapeurs chimiques
  • Compatible with PRO2000 filter range (gas, particle and combined)
  • Central phonic membrane for easy communication
  • Compatible with powered air equipment
  • Internal mask with non-return and anti-fog valves, reduces CO2
  • Fully adjustable 5 points harness for improved operating comfort
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Sigma self-contained breathing apparatus from SCOTT Safety combines highest respiratory protection levels to a cost-effective and user-friendly equipment to meet industrial and marine sectors requirements.

  • High performance pneumatic system
  • Ultra-compact demand valve triggered from first breath
  • Lighweight and ergonomic backplate and fireproof harness
  • Possibility to switch to demand constant flow
  • Large range of full face masks: Vision 3, Promask PP and Panaseal
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Self-contained breathing apparatus – SIGMA

Sigma self-contained breathing apparatus from SCOTT Safety combines highest respiratory protection levels to a cost-effective and user-friendly equipment to meet industrial and marine sectors requirements.

Self-contained breathing apparatus SIGMA
  • High performance pneumatic system
  • Ultra-compact demand valve triggered from first breath
  • Lighweight and ergonomic backplate and fireproof harness
  • Possibility to switch to demand constant flow
  • Large range of full face masks: Vision 3, Promask PP and Panaseal
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The Proflow2 PAPR is a compact and lightweight device featuring a curved backplate for user comfort during long-term applications. This powered air purifying respirator is available in 120L/min or 160L/min versions.

  • complete Scott Safety PAPR powered-air-purifying Proflow2
  • DIN40 standard filters compatible with single-cartridge masks.
  • From 7 to 15 hours runtime depending on the face piece.
  • 70 dB audible low battery alarm.
  • Compatible with many face pieces.
  • Certifications: complies with EN12941 and 12942 standards.
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Powered air purifying respirator PROFLOW 2

The Proflow2 PAPR is a compact and lightweight device featuring a curved backplate for user comfort during long-term applications. This powered air purifying respirator is available in 120L/min or 160L/min versions.

complete Scott Safety PAPR powered-air-purifying Proflow2
  • DIN40 standard filters compatible with single-cartridge masks.
  • From 7 to 15 hours runtime depending on the face piece.
  • 70 dB audible low battery alarm.
  • Compatible with many face pieces.
  • Certifications: complies with EN12941 and 12942 standards.
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